Simultaneolls spectrophotometric determination of molybdenum ( VI ) and titanium ( IV ) using 2 , 4 - dihydroxybenzaldehyde isonicotinoyl hydrazone
نویسندگان
چکیده
Determination of molybdenum(VI) by direct spectrophotometry and simultaneous determination of molybdenum(VI) and titanium(IV) are reported. Molybdenum(VI) gives a golden yellow colour with 2,4dihydroxybenzaldehyde isonicotinoyl hydrazone with a 1:2 metal-reagent stoichiometry at pH 1.5. The complex shows an absorption maximum at 445 nm with molar absorptivity and Sandell's sensitivity of 1.02x10 I mor l cmI and 0.0094 ~g cmrespectively. Beer's law is obeyed in the range 0 .3-6.0 ~g mlI of Mo(VI) . Titanium(lV) and molybdenum(VI) have been determined simultaneously by measuring the absorbance of the solution mixture at 445 nm and 560 nm respectively. The method has been applied for the simultaneous determination of molybdenum(VI) and titanium(IV) in steel samples.
منابع مشابه
Non-Extractive Spectrophotometric Determination of U(VI) Using 5-Bromo Salicylaldehyde Isonicotinoyl Hydrazone in Environmental, Phosphate Rocks and Fertilizer Samples
A highly sensitive and selective spectrophotometric method was developed for the determination of trace amount of uranium (VI) in water samples in aqueous DMF medium. The uranyl ion forms a pale yellow colored complex with 5-Bromo salicylaldehyde isonocotinoyl hydrazone (5-BrSAINH) in an acidic buffer of pH 5.0. The complex has an absorbance maximum at 395nm, was stable for more than 72 hours. ...
متن کاملSimultaneous determination of titanium and molybdenum in alloy steels using derivative spectrophotometry in neutral micellar medium
A simple, selective and sensitive spectrophotometric method has been developed for the individual and simultaneous determination of Ti(IV) and Mo(VI) using salicylaldehyde p-hydroxybenzoylhydrazone (SAPHBH) in presence of Triton X100, without any prior separation. Beer’s law is obeyed between 0.15-2.0 and 0.20-2.51 μgmL concentration of Ti(IV) and Mo(VI) at 470 and 410 nm, respectively. The mol...
متن کاملDirect, derivative spectrophotometric determination of micro amounts of Vanadium (V) by 5-bromo salicylaldehyde isonicotinoyl hydrazone
A simple and highly selective spectrophotometric method has been developed for the determination of trace amounts of V (V) using newly synthesized reagent 5-bromo salicylaldehyde isonicotinoyl hydrazone (5BrSAINH) in aqueous DMF medium. Vanadium (V) forms a brown colored soluble complex with 5-BrSAINH in the pH range 1.0-5.0. The complex shows maximum absorbance at 400nm in the pH range 4.5-5.5...
متن کاملSpectrophotometric Determination of Trace amounts of Molybdenum(VI) Using 4-Hydroxybenzaldehydethiosemicarbazone
The reagent 4-hydroxybenzaldehyde thiosemicarbazone (4-HBTS) has been used for the determination of Mo(VI) by spectrophotometric method. The reagent 4-HBTS gives green colour with Mo(VI) solution of weak acidic medium and the maximum absorbance was observed at 365nm, in acidic buffer p H 6.0. The molar absorptivity and Sandell’s sensitivity of Mo(VI)4-HBTS complex are 1.25 x 10 L mol cm and 0.0...
متن کاملDirect and Derivative Spectrophotometric Determination of Cobalt (II) using 3,4-DihydroxyBenzaldehyde-1-(3-Chloro-2-Quinoxalinyl)Hydrazone(DHBCQH) in Presence of Micelle Medium
A rapid and sensitive method has been developed for the determination of Cobalt(II) based on complexation reaction between the metal ion and 3,4,-dihydroxybenzaldehyde-1-(3Chloro-2-Quinoxalinyl)Hydrazone (DHBCQH) in the presence of non-ionic surfactant Tween-80. The important parameters affecting the analytical procedure were optimized. Absorption maximum for a ternary complex was noted at 450 ...
متن کامل